Quality evaluation parameter and classification model for effluents of wastewater treatment plant based on machine learning.

• An effluent quality evaluation parameter system was developed by machine learning. • Data containing 110 parameters from 176 WWTP effluents across China were measured. • Four clustering algorithms were trained in 31 scenarios to obtain optimal scenarios. • Five classification algorithms trained 65 well-performing models in 13 optimal scenarios. • Based on parameter system, a water quality classification method was developed. With the growing consensus of emerging pollutants and biological toxicity risks in wastewater treatment plant (WWTP) effluents, traditional water quality management based on general chemical parameters no longer meets the new challenges. Here, a first-hand dataset containing 9 conventional parameters, 22 mental and inorganic ions, 25 biotoxicity parameters, and 54 emerging pollutants from effluents of 176 municipal WWTPs across China were measured. Four clustering algorithms and five classification algorithms were applied to 65 well-performing models to determine a novel evaluation parameter system. A total of 14 parameters were selected by semi-supervised machine learning, including TN, TP, NH 4 +-N, NO 2 --N, Se, SO 4 2-, Caenorhabditis elegans body width, 72 hpf zebrafish embryo hatching rate, tetracycline, acetaminophen, gemfibrozil (Lopid), PFBA, PFHxA, and HFPO-DA. These parameters were then used to construct a Healthy Effluent Quality Index model (HEQi). The application efficiency of HEQi was compared with other common methods such as the Water Quality Index (WQI), Fuzzy Synthesized Evaluation (FSE), and Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) in classifying 176 effluents. Results implicated that under the new evaluation criteria, the major task in North and Northeast China remains to reduce the conventional parameters, especially NO 2 --N. However, it is necessary to strengthen the removal of biotoxicity and emerging pollutants in parts of Central and Eastern China. This study offers new methodological tools and scientific insights for improving water quality assessment and safe discharge of wastewater. [Display omitted] [ABSTRACT FROM AUTHOR]