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Force density induced by preferential adsorption in a near-critical binary fluid mixture subject to the Soret effect.

Authors :
Fujitani, Youhei
Source :
Journal of Chemical Physics. 11/28/2024, Vol. 161 Issue 20, p1-15. 15p.
Publication Year :
2024

Abstract

We assume that two parallel plates are immersed in a binary fluid mixture lying in the one-phase region near the demixing critical point and that the surface of each plate attracts the mixture components differently via short-range interactions. It is known that the composition inhomogeneity caused by the difference can induce a force exerted on the plate at equilibrium. In the present study, we investigate how a temperature gradient imposed vertically on the plates changes the induced force by calculating the composition profile subject to the Soret effect. Numerically solving the derived differential equation, we show that a temperature gradient within the critical regime can change the force distinctly from its equilibrium value and can make the force direction opposite to the one at equilibrium. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
161
Issue :
20
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
181152683
Full Text :
https://doi.org/10.1063/5.0220373