Temperature-triggered liquid metal actuators for fluid manipulation by leveraging phase transition control.

Small-scale pumps for controlling microfluidics have promising applications in drug delivery and chemical assays. Liquid metal (LM) demonstrates excellent flow pumping performance due to its simple structure and the electrocapillary effect under an electric field. However, LM droplets risk escaping from constrained structures, which can lead to pump failure. Temperature regulation is also a critical parameter in optimizing chemical reactions in fluidic systems, however, integrating it into a compact system remains challenging. Here, we develop a temperature-triggered gallium-based actuator (TTGA) by introducing a gallium (Ga) droplet wetted on a copper (Cu) plate as the core element for flow actuation. The Cu plate prevents the Ga droplet from escaping the chamber and significantly increases the flow rate. By leveraging the electrochemical method to inhibit the supercooling effect of Ga, the TTGA enables activation/deactivation for flow actuation at different temperatures. We investigate the impact of electrode position, solution concentration, and applied voltage on TTGA's pumping efficiency. By dynamically tuning the Ga droplet's temperature to control phase transition, TTGA allows for accurate flow actuation control. Furthermore, placing Ga and eutectic Ga-indium (EGaIn) droplets in different channels enables the expected flow divergence for fluids with different temperatures. The development of TTGA presents new opportunities in microfluidics and biomedical treatment. [ABSTRACT FROM AUTHOR]