Infiltration of secondary treated wastewater into an oxic aquifer: Hydrochemical insights from a large-scale sand tank experiment.

• A unique experimental facility was built to assess MAR with STWW effluents. • Mixing zone of infiltrated STWW and resident groundwater is of special relevance. • Conservative model delineates processes of nutrients in capillary fringe and mixing zone. • Elevated concentrations of phosphate in STWW might trigger mobilisation of As. To mitigate groundwater level decline, managed aquifer recharge (MAR) with secondary treated wastewater (STWW) is increasingly considered and implemented. However, the effectiveness and potential risks of such systems need evaluation prior to implementation. In this study, we present a large-scale sand tank experiment to analyse processes related to the infiltration of real STWW through the vadose zone and subsequent mixing with oxic native groundwater. The varying composition of STWW from 15 infiltration cycles over six months of operation and the retention times were the main drivers of the observed processes, which were characterized by a wide range of analytical techniques such as in situ high-resolution oxidation–reduction potential (ORP) measurements, closed mass balances of solutes, characterization of dissolved organic carbon (DOC), stable nitrate isotopes analysis, as well as numerical flow and transport modelling. Depending on the composition and infiltration rates of the STWW, both nitrification and denitrification could be observed, even simultaneously at different locations in the tank. Furthermore, due to the variability of the real STWW we observed enhanced arsenic mobilisation during times of elevated phosphate concentrations of the infiltrating STWW. Additionally, uranium was mobilised in our experimental system via carbonate mineral dissolution caused by the infiltrating STWW which was undersaturated of calcite for all infiltration cycles. Overall, our results showed the importance of conducting studies with waters of complex matrix, such as real STWW, and considering mixing with groundwater to assess the full range of possible processes encountered at MAR field sites. [Display omitted] [ABSTRACT FROM AUTHOR]