Mechanically durable plant-based composite surface towards enhanced antifouling properties.

Rough surface structures filled with CW coating and grafted with the PDMS polymers were used to design the plant-based composite CW&PDMS coating that exhibit satisfactory antifouling properties and mechanically durable. [Display omitted] • Plant-based composite antifouling surfaces were successfully prepared. • The as-prepared surfaces have preferable mechanically durable properties. • The surfaces demonstrate excellent antibacterial and antifouling properties. The biofouling adhering to underwater facilities has a negative impact on the environment, energy, and economic development. However, conventional anti-adhesion organic silicon and organic fluorine materials often have poor adhesion properties and mechanical stability when combined with substrates. This work presents a novel strategy for preparing composite antifouling coatings that low surface energy plant-based carnauba wax (CW) covering through rough substrates and chemically bond with flexible polydimethylsiloxane (PDMS) oligomers or polymers. The CW coating adheres strongly to the substrate owing to the mobility of the liquated CW, which flows into the micro-nano structure of the substrate and solidifies on the solid surface. The polymerization reaction of (PDMS) oligomers compounded the coating, thereby creating a composite coating with superior lubricating and antifouling properties. This distinctive bonding process imbued the coating with exceptional characteristics, including remarkable mechanical stability in destructive tests as well as an impressive ability to repel fouling, such as protein attachment, bacterial adhesion, diatom deposition, and biofilm formation. This work systematically investigated the impact of the composition and structure of composite materials on their mechanical stability and resistance to fouling, and developed high-performance antifouling coatings in the real world. [ABSTRACT FROM AUTHOR]