Rotor proliferation promotes high-brightness AIE of iridium emitter accomplishing high-contrast luminous imaging of latent fingerprints to level 3 details.

[Display omitted] • Iridium developer with high-brightness AIE is created. • High-contrast LFP luminous imaging to level 3 details is achieved. • Exceptional aging resistance and repeatability are demonstrated by LFPs. • Imaging mechanism of LFPs driven by vdWs force is confirmed. Luminous imaging of latent fingerprints (LFPs) necessitates the possession of high-brightness aggregation-state luminescence by developers to ensure sufficient imaging contrast and resolution. A novel strategy involving incremental rotor modification is presented for AIE activation of the iridium developer. The rotor proliferation prominently improves the rotational activity of groups and facilitates high-efficiency RIM, thereby prompting the AIE activation of iridium developer with high luminous efficiency. Subsequently, a prompt, high-contrast, and robust LFP imaging protocol is developed utilizing the high-brightness AIE-active iridium developer. This innovative protocol realizes the luminous imaging and quantification of microscopic features in fingerprint ridges and furrows, including ridge widths, edge morphology of ridges, included angles, pores, and pore pitches with exceptional imaging contrast and refined detail resolution. Moreover, it allows for accurate identification of individual traits across diverse substrates without any pre-/post-processing to LFPs. The high-brightness AIE-active iridium developer provides outstanding aging resistance to developed fingerprints, thereby strongly supporting the acquisition, transfer, and preservation of fingerprint evidence. The luminous imaging protocol of LFPs based on high-brightness AIE exhibits robust adaptability to actual scenes and offers a premium scheme for facilitating forensic investigation. [ABSTRACT FROM AUTHOR]