High-performance carbon molecular sieve membrane derived from PEK-N polymer for CO2 separation.

Carbon molecular sieve (CMS) membranes demonstrate promising economic and environmental advantages in gas separation applications. In this work, we synthesized a novel polymer precursor of PEK-N and utilized it to fabricate a series of PEK-N derived CMS membranes. With varying carbonization temperature and time, the pore structures and gas separation performance were finely tuned. The gas separation properties of membranes with different carbonization temperature were comprehensively evaluated. In particular, by carbonizing the sample at 650 °C for 1 h, PEK-N derived CMS membranes (CMS-650-1) achieved the highest CO 2 permeability around 2176 Barrer, and selectivities of 48.2 for CO 2 /N 2 and 57.8 for CO 2 /CH 4 in their gas mixtures. Our study suggests that the use of rationally designed polymers has the potential to bring about high gas separation performance for polymer-derived carbon molecular sieve membranes. This study explores the use of a novel polymer of polyaryletherketone bearing tertiary amine group (PEK-N) for preparing carbon molecular sieve membranes through control of carbonization temperature and time. The optimized CMS membrane (CMS-650-1) exhibited a CO 2 permeability around 2176 Barrer, and CO 2 /N 2 and CO 2 /CH 4 gas selectivities of 48.2 and 57.8, respectively. [Display omitted] • Polyaryletherketone bearing tertiary amine group polymer was synthesized. • CMS membranes were fabricated using PEK-N polymer. • The structural features of CMS membranes could be tuned by adjusting the carbonization temperature and time. • The CMS membrane exhibited high separation performance for CO 2 /N 2 and CO 2 /CH 4. [ABSTRACT FROM AUTHOR]