Kinetics of formation, microstructure, and properties of monolithic forsterite (Mg2SiO4) produced through solid-state reaction of nano-powders of MgO and SiO2.

The synthesis of forsterite can be challenging because the initial oxides react slowly and undesirable compounds like enstatite (MgSiO 3) can form instead of forsterite (Mg 2 SiO 4). Although several methods have been developed to overcome these challenges, the synthesis of forsterite using the solid-state reaction of nanopowders has not been investigated. This study aims to explore the possibility of producing forsterite by reacting MgO and SiO 2 nano-powder. The initial oxides were wet ball milled, dried, and reaction sintered. Spectroscopy and microscopy methods were used to analyze the formed phases and study the formation kinetics. The density, coefficient of thermal expansion (CTE), and hardness of sintered samples were measured using a densimeter, a dilatometer, and a hardness tester, respectively. The results demonstrated that it is possible to synthesize forsterite by solid state reaction of pure MgO and SiO 2 nano-powders. The reaction between the two compounds begins at a temperature as low as 860 °C and leads to the formation of forsterite by a two-step formation mechanism. The first reaction involves the reaction of MgO and SiO 2 to form enstatite, and the second one produces forsterite as a result of enstatite reacting further with MgO. The activation energy values ranged from 1028.89 to 1105.655 kJ/mol for the formation of forsterite, and from 456.316 to 488.08 kJ/mol for the formation of enstatite. Monolithic forsterite was completely formed at a low temperature of 1200 °C for a relatively short duration of 2 h. The sample sintered at 1400 °C for 2 h, had a density of 2.96 g/cm3, a Vickers hardness of 7.64 GPa, and a coefficient of thermal expansion of 10.24 × 10−6/K measured in the temperature range of 200–1300 °C. [ABSTRACT FROM AUTHOR]