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Investigation of Structural and Magnetic Properties of Lead-Free NCFO-BTO Composites.

Authors :
Naveen, P.
Reddy, K. Damodar
Ramesh, T.
Reddy, V. Raghavendra
Raja, M. Manivel
Kumar, N. Pavan
Source :
Journal of Superconductivity & Novel Magnetism. Oct2024, Vol. 37 Issue 8-10, p1701-1711. 11p.
Publication Year :
2024

Abstract

Compared to single-phase multiferroic materials, multiferroic (MF)-magnetoelectric (ME) composites, which combine magnetic and ferroelectric materials, show improved (many orders of magnitude) ME coupling and a higher operating temperature (beyond room temperature). In the present study, lead-free multiferroic Ni0.5Co0.5Fe2O4/BaTiO3 (NCFO/BTO) composites with different weight percentages were prepared through the solid-state reaction approach. The phase purity and structural confirmation were carried out using X-ray diffractograms. The XRD peak shifting in the composites has been observed, and it is attributed to the formation of residual stresses/strains during the sample's grinding, heating, and freezing processes. Fourier-transformative infrared spectroscopy confirmed the presence of metal-oxygen bonds in spinel NCFO and Ti-O and Ba-O bonds in perovskite BaTiO3. UV-vis spectra disclose the energy gap values of the magnetoelectric composites. It has been found that the energy gap values for pure ferrite are 1.53 eV, the pure ferroelectric phase is 2.99 eV, and the composites possess the Eg values of 1.78 eV, 2.33 eV, 2.77 eV with decreasing ferrite concentration. The M-H hysteresis loops reveal the ferromagnetic nature of pure ferrite as well as the presence of ferromagnetism in composites. The magnetic moment of the NCFO has been found as 2.26 µB and it further decreased to 0.59 µB for the 0.25NCFO-0.75BTO compound. The magneto crystalline anisotropy has been calculated using the law of approach (LA) method and the details are discussed in the paper. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15571939
Volume :
37
Issue :
8-10
Database :
Academic Search Index
Journal :
Journal of Superconductivity & Novel Magnetism
Publication Type :
Academic Journal
Accession number :
180268702
Full Text :
https://doi.org/10.1007/s10948-024-06809-3