Back to Search Start Over

Long ranged stress correlations in the hard sphere liquid.

Authors :
Grimm, Niklas
von Bischopinck, Martin
Zumbusch, Andreas
Fuchs, Matthias
Source :
Journal of Chemical Physics. 10/14/2024, Vol. 161 Issue 14, p1-16. 16p.
Publication Year :
2024

Abstract

The smooth emergence of shear elasticity is a hallmark of the liquid to glass transition. In a liquid, viscous stresses arise from local structural rearrangements. In the solid, Eshelby has shown that stresses around an inclusion decay as a power law r−D, where D is the dimension of the system. We study glass-forming hard sphere fluids by simulation and observe the emergence of the unscreened power-law Eshelby pattern in the stress correlations of the isotropic liquid state. By a detailed tensorial analysis, we show that the fluctuating force field, viz., the divergence of the stress field, relaxes to zero with time in all states, while the shear stress correlations develop spatial power-law structures inside regions that grow with longitudinal and transverse sound propagation. We observe the predicted exponents r−D and r−D−2. In Brownian systems, shear stresses relax diffusively within these regions, with the diffusion coefficient determined by the shear modulus and the friction coefficient. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
161
Issue :
14
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
180250739
Full Text :
https://doi.org/10.1063/5.0225890