Synthesis, characterization, and crystal structure of hexakis(1-methyl-1H-imidazole-jN3 )zinc(II) dinitrat.

The synthesis of the title compound, [Zn(C4H6N2)6](NO3)2, is described. This complex consists of a central zinc metal ion surrounded by six 1-methylimidazole ligands, charge balanced by two nitrate anions. The complex crystallizes in the space group P3. In the crystal, the nitrate ions are situated within the cavities created by the [Zn(N-Melm)6] 2+ cations, serving as counter-ions. The three oxygen atoms of the nitrate ion engage in weak C—H...O interactions. In addition to single-crystal X-ray diffraction analysis, the complex was characterized using elemental analysis, ¹ H NMR, 13C NMR, and FTIR spectroscopy. [ABSTRACT FROM AUTHOR]