Enhanced efficiency and stability in the degradation of triazophosphorus pesticides by Al6Si2O13/WO2.72 nanocomposites through synergistic action of S-scheme heterojunction and oxygen vacancies.

[Display omitted] • The Al 6 Si 2 O 13 /WO 2.72 nanocomposites exhibits excellent photocatalytic activity and stability in degrading triazophos pesticides, reducing the rate from 100.0% to 13.7% in 140.0 min. • The S-scheme heterojunction significantly enhances photocatalytic performance by improving charge separation and minimizing recombination. • Abundant oxygen vacancies combined with the S-scheme heterojunction accelerate charge separation, further enhancing photocatalytic degradation activity. The environmental contamination caused by organophosphorus pesticides (for example, triazophos) is an escalating concern. To mitigate this issue, this study introduces a novel Al 6 Si 2 O 13 /WO 2.72 (ASO/WO) nanocomposite photocatalyst, which markedly enhances the photocatalytic degradation of triazophos. The optimized nanocomposite material with a 60.0 % ASO loading (60-ASO/WO) achieves a degradation rate of 86.3 % for triazophos within 140.0 min, marginally exceeding 60-ASO/WO 3 (72.6 %) and significantly outperforming individual ASO (65.0 %), WO (59.5 %), and WO 3 (56.2 %). This catalyst retains 88.9 % of its activity after five cycles, showcasing exceptional efficiency and stability. Additionally, its electrochemical surface area (ECSA, 310.0 cm2), total organic carbon (TOC, removal rate of 73.7 %), photocurrent, and electrochemical impedance are all optimal. X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance (EPR), and theoretical calculations elucidate the critical role of oxygen vacancies and the S-scheme heterojunction in augmenting charge separation and photocatalytic performance, corroborating the synergistic effect of oxygen defects and the S-scheme. While individual factors can enhance photocatalytic activity, their combination results in a more pronounced effect. Liquid chromatography-mass spectrometry (LCMS) identifies the principal degradation intermediates, including 1-phenyl-3-hydroxy-1, 2, 4-triazole, diethyl thiophosphate, and 3, 5, 6-trichloro-2-pyridinol, underscoring the material's potential in environmental remediation. [ABSTRACT FROM AUTHOR]