Electrochemical C3‐Fluoroalkoxylation of Quinoxalin‐2(1H)‐ones with Fluoroalkyl Alcohols for the Synthesis of 3‐Fluoroalkoxylated Quinoxalin‐2(1H)‐ones.

Herein, we report the first electricity‐driven and metal‐free C(3)−H fluoroalkoxylation of quinoxalin‐2(1H)‐ones with both α‐monosubstituted and α,α‐disubstituted fluoroalkyl alcohols. This strategy features the advantages of convenience, mildness, effEctiveness and broad substrate practicality for synthesizing a new type of 3‐fluoroalkoxylated quinoxalin‐2(1H)‐ones. [ABSTRACT FROM AUTHOR]