PdS-ZnS-Doped Electrospun Polymer Nanofibers as Effective Photocatalyst for Hydrogen Evolution.

Poly(vinyl acetate) nanofibers doped with PdS-ZnS nanoparticles (PdS-ZnS/PVAc nanofibers) were fabricated via an electrospinning technique. PdS-ZnS nanoparticles were in situ synthesized by adding (NH4)2S solution to poly(vinyl acetate)/zinc acetate/palladium acetate solution. Electrospinning of the formed colloidal solution led to the formation of poly(vinyl acetate) nanofibers containing uniformly distributed PdS-ZnS nanoparticles. The prepared samples were characterized by field emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy and Fourier transform infrared spectroscopy. In photocatalytic activity investigation, the PdS-ZnS/PVAc nanofibers showed remarkably enhanced performance towards water photosplitting under solar irradiation compared to the ZnS/PVAc nanofibers. This enhanced performance is attributed to the synergistic effects of heterostructured PdS-ZnS nanoparticles, which can improve photogenerated charge migration and solar light absorption. [ABSTRACT FROM AUTHOR]