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Enhancing the magnetization, dielectric parameters and elastic parameters while simultaneously minimizing coercivity and dielectric loss in nickel-manganese-cobalt ferrite nanoparticles through Ce3+ doping assistance.

Authors :
Abdo, M.A.
Mansour, S.F.
Al-Bassami, N.S.
Source :
Ceramics International. Nov2024:Part C, Vol. 50 Issue 21, p43433-43441. 9p.
Publication Year :
2024

Abstract

This study focuses on examining how the rare-earth cerium incorporation affects the magnetic, dielectric, and mechanical characteristics of Ni 0.5 Mn 0.25 Co 0.25 Ce x Fe 2-x O 4 spinel ferrite nanoparticles. (NMCCF). The nanoferrite Ni 0.5 Mn 0.25 Co 0.25 Ce 0.04 Fe 1.96 O 4 acquires the lowest coercivity of 567 Oe and the highest saturation magnetization of 52.23 emu/g. All the NMCCFx nanoferrites exhibit a microwave frequency range of 9.47–11.55 GHz, suggesting potential applications in longitudinal recording media and microwave absorbance. Moreover, the nanoferrite Ni 0.5 Mn 0.25 Co 0.25 Ce 0.1 Fe 1.9 O 4 demonstrates the highest dielectric value of 1871, with an enhancing ratio of 754 %, excellent conductivity at 3.12 μ(Ω.m)−1 along with a remarkably enhanced percentage of 369 %. Additionally, it shows a loss factor of 2.17, with a notable improvement percentage of 26 % compared to the pure NMCCF0 sample at 50 Hz and room temperature. The elastic moduli (longitudinal, shear, Young, and bulk) of the Ni 0.5 Mn 0.25 Co 0.25 Ce 0.1 Fe 1.9 O 4 nanoferrite increased from 1.21 to 2.77 GPa, 0.25–0.76 GPa, 0.68–1.99 GPa, and 0.87–1.75 GPa, respectively. This study introduces a novel approach to Ni–Mn–Co–Ce spinel nanoferrites, highlighting their magnetic, electrical, and mechanical characteristics, which hold promise for electronic and high-frequency device applications. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
02728842
Volume :
50
Issue :
21
Database :
Academic Search Index
Journal :
Ceramics International
Publication Type :
Academic Journal
Accession number :
179973064
Full Text :
https://doi.org/10.1016/j.ceramint.2024.08.194