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Photoinduced Transition‐Metal‐Free Chemodivergent Phosphorylation‐Peroxidation and Oxyphosphorylation of Alkenes.
- Source :
-
Advanced Synthesis & Catalysis . 9/17/2024, Vol. 366 Issue 18, p3860-3867. 8p. - Publication Year :
- 2024
-
Abstract
- A visible‐light‐promoted chemodivergent phosphorylation‐peroxidation and oxyphosphorylation of alkenes with phosphine oxides and HOOtBu was realized under transition‐metal‐free conditions. Using the commercially available Eosin Y as a SET‐photocatalyst, the β‐peroxy‐phosphine oxides were selectively obtained with a catalytic amount of base, while the addition of acid led to the exclusive formation of β‐keto‐phosphine oxides control experiments showed that Eosin Y could also act as a HAT‐catalyst to induce the O−O bond cleavage of peroxides under acidic conditions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *EOSIN
*ALKENES
*OXIDES
*PHOSPHINE oxides
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 366
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 179963007
- Full Text :
- https://doi.org/10.1002/adsc.202400606