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Pd(II)‐Catalyzed Formal [5+2]‐Carbocyclization of Ortho‐Aryl‐Substituted Arylaldehydes with Allylic Alcohols.

Authors :
Wang, Chengjie
Jiang, Huanfeng
Zeng, Wei
Source :
Advanced Synthesis & Catalysis. 9/17/2024, Vol. 366 Issue 18, p3875-3880. 6p.
Publication Year :
2024

Abstract

A Pd(II)‐catalyzed formal [5+2] coupling‐cyclization of 2‐arylbenzaldehydes with allylic alcohols has been developed. The method provides an efficient approach to access diaryl‐fused cycloheptene skeletons via traceless α‐amino acid‐assisted Csp2−H activation process. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*SKELETON
*ALLYL alcohol

Details

Language :
English
ISSN :
16154150
Volume :
366
Issue :
18
Database :
Academic Search Index
Journal :
Advanced Synthesis & Catalysis
Publication Type :
Academic Journal
Accession number :
179963002
Full Text :
https://doi.org/10.1002/adsc.202400568