An effective turn-on/off rodamine-encapsulated UiO-67-NH2 fluorescent probe for simultaneous As5+/Fe3+ detection.

The development of metal ion detection probes with high sensitivity and selectivity is of utmost importance for the promotion of public health and environmental sustainability. In this work, a series of ratiometric fluorescent probes (RhB@UiO-67-NH 2) were successfully prepared using a one-pot method for the detection of metal ions, particularly As5+ and Fe3+. Notably, the ratiometric fluorescent probe RhB@UiO-67-NH 2 (1:4) demonstrates dual functionality as a Fe3+ turn-off probe and an As5+ turn-on probe. The limits of detection (LODs) for As5+ and Fe3+ using RhB@UiO-67-NH 2 (1:4) were determined to be 0.521 μM (39.03 ppb) and 0.107 μM (5.97 ppb), respectively, which were the lowest records of reported LMOFs so far. The fluorescence quenching of Fe3+ can be attributed to various mechanisms such as fluorescence resonance energy transfer (FRET), photoinduced electron transfer (PET), and competitive absorption (CA). Additionally, the fluorescence enhancement of As5+ is primarily due to absorbance-caused enhancement (ACE) and PET. Moreover, the composite material RhB@UiO-67-NH 2 (1:4) exhibited excellent anti-interference capability and reproducibility for detecting Fe3+ and As5+. The removal efficiency of As5+ by RhB@UiO-67-NH 2 (1:4) exceeded 50.9 % when the initial concentration of As5+ was below 20 mg/L. This work presents a valuable reference for future investigations and utilization of As5+ and Fe3+ sensing. RhB@UiO-67-NH 2 serves as an effective turn-on/off fluorescent probe for simultaneous As5+/Fe3+ identification. [Display omitted] • The ratio fluorescent probe RhB@UiO-67-NH 2 (1:4) can effectively detect As5+/Fe3+. • LODs of As5+ and Fe3+ for RhB@UiO-67-NH 2 (1:4) were 0.521 and 0.107 μM, respectively. • DFT simulation provided theoretical guidance for sensing mechanisms. • The fluorescence enhancement of As5+ was primarily due to ACE and PET. • The fluorescence quenching of Fe3+ was attributed to FRET, PET and CA mechanisms. [ABSTRACT FROM AUTHOR]