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Solid-state [2+2] photodimerization of eniminium salts: stereoselective syntheses of 1,3-diacetylcyclobutanes.
- Source :
-
Chemical Communications . 9/16/2024, Vol. 60 Issue 72, p9821-9824. 4p. - Publication Year :
- 2024
-
Abstract
- Solid-state [2+2] photodimerization of eniminium ions oriented in a head-to-tail manner controlled by cation–π interactions produced synHT dimers in high yields. As the resulting dimer is readily converted to 1,3-diacetylcyclobutane, the iminium serves as a removable orientation-controlling group for the conjugated ketones. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PHOTODIMERIZATION
*DIMERS
*KETONES
*IONS
*SALTS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 72
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 179485416
- Full Text :
- https://doi.org/10.1039/d4cc03691c