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A selective photoinduced radical O-alkenylation of phenols and naphthols with terminal alkynes.
- Source :
-
Chemical Communications . 9/16/2024, Vol. 60 Issue 72, p9813-9816. 4p. - Publication Year :
- 2024
-
Abstract
- The visible light-promoted O-alkenylation of phenols and naphthols with terminal alkynes is achieved using 2,4,6-tris(4-fluorophenyl)pyrylium tetrafluoroborate (T(p-F)PPT) as a photocatalyst at room temperature without the need of any external ligand or additive. Apart from its excellent functional group tolerance, the protocol described herein represents an appealing alternative strategy to classical transition-metal catalysed hydroarylation reactions. Mechanistic investigations revealed that the reaction involves a radical pathway. The utility of the hydroarylated products for the synthesis of fused benzofurans via a one-pot annulation was also demonstrated. Herein, we report the first intermolecular radical hydroarylation of alkynes. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BENZOFURAN synthesis
*RADICALS (Chemistry)
*FUNCTIONAL groups
*ALKYNES
*PHENOLS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 72
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 179485393
- Full Text :
- https://doi.org/10.1039/d4cc02555e