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Regulation of nanoscale Mg/V incoherent interface interactions to enhance hydrogen storage properties in Mg/V multilayer films.
- Source :
-
Journal of Alloys & Compounds . Nov2024, Vol. 1005, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- Magnesium-based materials offer a promising, cost-effective, and high-capacity solution for hydrogen storage. However, their slow kinetics and elevated absorption/desorption temperatures limit their large-scale application. In this study, a series of Mg 1- x /V x (x = 0.05, 0.10, 0.15, 0.20) multilayer films were designed and fabricated using an ultra-high vacuum magnetron sputtering technique. Transmission electron microscopy (TEM) analysis revealed the presence of a discontinuous nanoscale V single-phase interlayer between the Mg layers, confirming the successful formation of Mg/V multilayer films. The surface of the deposited films predominantly consists of hexagonal particles of varying sizes stacked upon one another. Upon hydrogenation, tetragonal rutile structures of MgH 2 and V 2 H were formed. The Mg 0.95 V 0.05 film absorbed 6.40 wt% hydrogen within 15 min at 150 °C and desorbed 0.34 wt% hydrogen within 1.8 h at the same temperature, with an initial dehydrogenation temperature of 79 °C. The activation energies for hydrogen absorption and desorption were estimated to be 60 ± 7 and 140 ± 10 kJ/mol H 2 , respectively, significantly lower than the corresponding values of 100 and 160 kJ/mol H 2 for conventional pure Mg/MgH 2. The enhanced hydrogen absorption performance was attributed to the catalytic effect of nanocrystalline V at the Mg/V incoherent interface, while the improved desorption performance was due to the synergistic catalytic effect of nanocrystalline V 2 H at the MgH 2 /V 2 H incoherent interface. DFT calculations indicated that the interaction at the Mg/V incoherent interface promoted H atom adsorption and diffusion, significantly enhancing the hydrogenation and dehydrogenation performance of the multilayer films. [Display omitted] • Mg/V multilayer films were designed and prepared using magnetron sputtering. • Structure and hydrogen storage properties of Mg/V multilayer films were studied. • DFT calculations revealed that the Mg/V interface strongly adsorbs H atoms. • V and its hydride-induced catalytic effect improve hydrogen absorption/desorption. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 1005
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 179465168
- Full Text :
- https://doi.org/10.1016/j.jallcom.2024.176162