Kaolin and zinc oxide supported PdCu catalysts as a superior catalyst in methanol oxidation reaction.

Electrocatalysts, which are important in increasing the efficiency of fuel cells, still have disadvantages such as low stability and high cost. To overcome these disadvantages, research on the synthesis of low-cost nanoparticle (NP) catalysts has been carried out. In this study, a new approach to develop a low-cost, high electrocatalytic activity and more stable catalyst was realized. In this context; kaolin ((Al 2 O 3 (SiO 2) 2 (H 2 O) 2)) and zinc oxide (ZnO) supported palladium-copper (PdCl 2 –CuCl 2) nanostructures were synthesized by chemical reduction technique. The particle sizes of the synthesized PdCu@kaolin and PdCu@ZnO NPs were found to be 12.02 nm and 23.02 nm, respectively, according to the Debye Scherrer formula. The PdCu@kaolin and PdCu@ZnO NPs obtained within the scope of the study were also used in the anodic oxidation of methanol (CH₃OH), a one-carbon organic compound. According to the results obtained, the current density for methanol oxidation peaks of PdCu@kaolin and PdCu@ZnO NPs were found to be 27.77 mA cm−2 and 41.52 mA cm−2, respectively. It was observed that the ZnO-supported nanoparticles provided 1.49 times higher electrocatalytic activity compared to the other one. The 500-cycle results showed that the ZnO-supported catalyst exhibited a continuously increasing current density. The tests also proved that the catalysts are diffusion-controlled systems and have high stability. Within the scope of the study, ZnO and Kaolin support not only decreased the cost of the catalyst but also significantly affected the electrocatalytic activity, offering better results than the commercial Pd/C catalyst. Cost-effective ceramic structures such as kaolin and ZnO were crucial to show high stability and electroactive behavior close to the literature. The current study has performed an important contribution to the literature on the use of ceramic materials in electrochemistry. • Synthesis of PdCu@kaolin and PdCu@ZnO NPs by chemical reduction. • High electrocatalytic activity of PdCu@kaolin and PdCu@ZnO NPs against methanol oxidation. • Cost-effective and highly stable catalysts. • Efficient anode catalysts for methanol fuel cells. [ABSTRACT FROM AUTHOR]