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Chiral Acetal‐Based Stereo‐Controlled Degradable Polymer Synthesis.

Authors :
Song, Dayong
Koo, Bonwoo
Kang, Houng
Seo, Kyeongdeok
Kim, Choeljae
Source :
Chemistry - A European Journal. 9/2/2024, Vol. 30 Issue 49, p1-8. 8p.
Publication Year :
2024

Abstract

The precise synthesis of chiral polymers remains a significant challenge in polymer chemistry, particularly for applications in advanced biomedical and electronic materials. The development of degradable polymers is important for eco‐friendly and advanced materials. Here, we introduce a stereo‐controlled degradable polymer via cascade enyne metathesis polymerization and enantioselective acetal synthesis through Pd‐catalyzed asymmetric hydroamination. This approach allows for the creation of chiral acetal‐based polymers with controlled stereochemistry and degradability, highlighting their potential for use in drug delivery and electronic applications. This concept article reviews the background, development, and potential applications of these stereo‐controlled degradable polymers. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
30
Issue :
49
Database :
Academic Search Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
179393615
Full Text :
https://doi.org/10.1002/chem.202402064