Hexavalent chromium scavenging performances of one-pot synthesized hydrous cerium-copper-mixed oxide from contaminated water with plausible mechanism.

Prolonged use of the chromate [Cr(VI)]-contaminated water originates severe health problems for the public. Thus, the societal urgency is a reusable and cost-effective material for efficient scavenging of Cr(VI) from contaminated industrial wastewater. Aiming this, we had targeted to prepare some cheap and effective materials for scavenging Cr(VI) from the contaminated water. Herein, we report the preparation of hydrous cerium-copper oxide (HCCO) with some tailored compositions and employed toward the abstraction of chromate from water solution. The HCCO (Ce: Cu = 1:4, mole/mole) has shown the highest Cr(VI) scavenging capacity. Experimentally, highest Cr(VI) abstraction efficiency is recorded at pH ~ 3.0 (508.853 mg. g−1 at 303 K). Kinetically, the Cr(VI) scavenging reaction with HCCO surfaces agrees better with the pseudo second-order model (R2 = 0.987) equation and the equilibrium Cr(VI) distribution data explain the Freundlich isotherm model (R2 = 0.998) equation, which anticipates the multi-layered adsorption on heterogeneous sites of the adsorbent. A negative value of the Gibbs free energy change indicates that the Cr(VI) adsorption over HCCO surfaces is spontaneous. The positive enthalpy change indicates the endothermic nature of the said reaction. HIGHLIGHTS: One-pot synthesis of hydrous Ce(IV)-Cu(II) oxide (HCCO) and characterizations. Systematic Cr(VI) scavenging from modeled ground water with HCCO. Best fit pseudo-second-order kinetic model, implying the chemisorption mechanism. Very high amount of Cr(VI) scavenging at ambient condition reported to be 508.85 mg.g−1. Coulombic interaction between HCCO and Cr(VI) is responsible for scavenging Cr(VI). [ABSTRACT FROM AUTHOR]