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Theorem on rates of alignment of electronegativities of atoms in the process of formation of a chemical bond in a binary molecule.

Authors :
Perfileev, Michael
Lyakishev, Vladislav
Source :
Journal of Mathematical Chemistry. Oct2024, Vol. 62 Issue 9, p2326-2333. 8p.
Publication Year :
2024

Abstract

This work is based on the productive idea of Mulliken about the alignment of electronegativities of atoms in the process of bond formation to their geometric mean value. The paper considers in detail the case of a binary molecule and obtains formulas for the dependence of the current values of the electronegativities of the two atoms forming the molecule on time, and finds a mathematical connection between the current and initial values of electronegativities. Also, in the work the theorem on the relation between the rates of alignment of electronegativities of atoms entering into chemical bonding is formulated and proved, and a special case of this theorem is considered. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
02599791
Volume :
62
Issue :
9
Database :
Academic Search Index
Journal :
Journal of Mathematical Chemistry
Publication Type :
Academic Journal
Accession number :
179277357
Full Text :
https://doi.org/10.1007/s10910-024-01655-z