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Testing the possibility of using UV–vis spectrophotometric techniques to determine non-absorbing analytes by inclusion complex competition in cyclodextrins
- Source :
-
Analytica Chimica Acta . Jul2005, Vol. 543 Issue 1/2, p282-290. 9p. - Publication Year :
- 2005
-
Abstract
- Abstract: In this paper, a general methodology to determine non-chromogenic compounds by UV–vis spectrophotometry given the competition of their inclusion complex in cyclodextrins with a structure-alike synthetic standard has been explored. The method was satisfactorily applied to quantify γ-lindane to levels as low as 0.05μgmL−1 in tap water spiked with standard by resolving the UV–vis spectra of the complex of the structure-alike chromogenic standard and HP-γ-cyclodextrin by partial least squares (PLS). [Copyright &y& Elsevier]
- Subjects :
- *SPECTROPHOTOMETRY
*SPECTRUM analysis
*CYCLODEXTRINS
*DEXTRINS
Subjects
Details
- Language :
- English
- ISSN :
- 00032670
- Volume :
- 543
- Issue :
- 1/2
- Database :
- Academic Search Index
- Journal :
- Analytica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 17918574
- Full Text :
- https://doi.org/10.1016/j.aca.2005.04.012