MOF-derived hollow octahedral CoxP/MOF-801 p-n heterojunction for efficient photocatalytic hydrogen production.

Hydrogen energy produced through photocatalytic water splitting is widely recognized as a viable solution to the depletion of non-renewable energy resources and ecological contamination concerns. This work designed and synthesized the MOF-derived hollow octahedral Co x P/MOF-801 p-n heterojunction photocatalyst. According to the result of hydrogen production test, the hydrogen production amount of Co x P/MOF-801-2 could reach 25.31 mmol g−1 under light irradiation for 5 h. The hollow octahedral structure and p-n heterojunction of the photocatalyst helped to enhance the light trapping ability and promote carrier transfer, resulting in improved performance of photocatalytic hydrogen production. To sum up, the design of hollow octahedral Co x P/MOF-801 photocatalyst effectively improved the photocatalytic hydrogen production performance. [Display omitted] • MOF-derived hollow octahedral MOF-801 was synthesized and modified with Co x P nanoparticles. • The p-n heterojunction inhibited the recombination of electrons and holes. • The Co x P/MOF-801 exhibited excellent hydrogen production activity and stability. [ABSTRACT FROM AUTHOR]