Back to Search
Start Over
A Practical Electrochemical Approach for Synthesizing Selenyl-Dihydrobenzofurans and Chromane with a Tetrasubstituted Carbon Center.
- Source :
-
Synthesis . Sep2024, Vol. 56 Issue 17, p2695-2702. 8p. - Publication Year :
- 2024
-
Abstract
- A straightforward and efficient electrochemical method for the anodic oxidative selenenylation of 2-(2-arylallyl)phenols and a 2-(3-arylbut-3-en-1-yl)phenol with diselenides under ambient air conditions has been outlined. This method allows for the synthesis of selenyl-dihydrobenzofurans and a chromane featuring a sterically hindered tetrasubstituted carbon center, demonstrated through 25 examples with yields reaching up to 98%. Initial mechanistic investigations suggest the likely participation of pivotal seleniranium cation species in regulating the reactivity. [ABSTRACT FROM AUTHOR]
- Subjects :
- *AIR conditioning
*CARBON
*PHENOL
Subjects
Details
- Language :
- English
- ISSN :
- 00397881
- Volume :
- 56
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Synthesis
- Publication Type :
- Academic Journal
- Accession number :
- 179020404
- Full Text :
- https://doi.org/10.1055/s-0043-1775373