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Construction of Bi/Bi2O3 particles embedded in carbon sheets for boosting the storage capacity of potassium-ion batteries.

Authors :
Tang, Yangyang
Cheng, Lu
Zheng, Junhao
Sun, Yingjuan
Li, Hongyan
Source :
Journal of Colloid & Interface Science. Nov2024, Vol. 674, p634-642. 9p.
Publication Year :
2024

Abstract

[Display omitted] • The Bi/Bi 2 O 3 nanoscale particles embedded in N -doped carbon sheets was fabricated. • Two-phase of Bi/Bi2O3 give an alloying/transformation dual-channel mechanism. • The Bi/Bi 2 O 3 @CN-700 anode exhibits visible potassium storage performance. Bismuth-based materials have attracted interest in potassium-ion batteries (PIBs). However, the large volume expansion prevents further use of bismuth-based materials for potassium storage. This work employs a two-step synthesis method to innovatively synthesize of Bi/Bi 2 O 3 nanoparticles assembled on N -doped porous carbon sheets (Bi/Bi 2 O 3 @CN). The layered structures with uniformly shaped and N -doped porous carbon skeleton buffer the expansion of Bi and the Bi/Bi 2 O 3 particles increase the capacity of potassium storage. In brief, the Bi/Bi 2 O 3 @CN served as anode in half-cell of PIBs have a good rate capacity of more than 234.7 mAh/g at 20 A/g. The specific capacity retention was 73 % compared with 322.16 mAh/g at 1 A/g, demonstrating good holding capacity for diverse current densities. The cycle also displays 163 mAh/g after 1500 cycles at 2 A/g in the KPF 6 metal salt solution, showing its potential as one of the anode materials in PIBs. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219797
Volume :
674
Database :
Academic Search Index
Journal :
Journal of Colloid & Interface Science
Publication Type :
Academic Journal
Accession number :
178884781
Full Text :
https://doi.org/10.1016/j.jcis.2024.06.207