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Construction of Bi/Bi2O3 particles embedded in carbon sheets for boosting the storage capacity of potassium-ion batteries.
- Source :
-
Journal of Colloid & Interface Science . Nov2024, Vol. 674, p634-642. 9p. - Publication Year :
- 2024
-
Abstract
- [Display omitted] • The Bi/Bi 2 O 3 nanoscale particles embedded in N -doped carbon sheets was fabricated. • Two-phase of Bi/Bi2O3 give an alloying/transformation dual-channel mechanism. • The Bi/Bi 2 O 3 @CN-700 anode exhibits visible potassium storage performance. Bismuth-based materials have attracted interest in potassium-ion batteries (PIBs). However, the large volume expansion prevents further use of bismuth-based materials for potassium storage. This work employs a two-step synthesis method to innovatively synthesize of Bi/Bi 2 O 3 nanoparticles assembled on N -doped porous carbon sheets (Bi/Bi 2 O 3 @CN). The layered structures with uniformly shaped and N -doped porous carbon skeleton buffer the expansion of Bi and the Bi/Bi 2 O 3 particles increase the capacity of potassium storage. In brief, the Bi/Bi 2 O 3 @CN served as anode in half-cell of PIBs have a good rate capacity of more than 234.7 mAh/g at 20 A/g. The specific capacity retention was 73 % compared with 322.16 mAh/g at 1 A/g, demonstrating good holding capacity for diverse current densities. The cycle also displays 163 mAh/g after 1500 cycles at 2 A/g in the KPF 6 metal salt solution, showing its potential as one of the anode materials in PIBs. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SOLUTION (Chemistry)
*ANODES
*POTASSIUM
*NANOPARTICLES
*SKELETON
Subjects
Details
- Language :
- English
- ISSN :
- 00219797
- Volume :
- 674
- Database :
- Academic Search Index
- Journal :
- Journal of Colloid & Interface Science
- Publication Type :
- Academic Journal
- Accession number :
- 178884781
- Full Text :
- https://doi.org/10.1016/j.jcis.2024.06.207