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Addition of diazonium salts to the coordinatively unsaturated core of a dinuclear organoruthenium complex.

Authors :
Mayer, Tobias
Mayer, Peter
Böttcher, Hans-Christian
Source :
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences. Jun2024, Vol. 79 Issue 5/6, p327-330. 4p.
Publication Year :
2024

Abstract

The reaction of [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)] (1) with the diazonium salts [PhN2]BF4 and [p-BrC6H4N2]BF4 in dichloromethane at T = 273 K was investigated. The oxidative addition afforded the products [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2Ph)]BF4 (2a) and [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2C6H4-p-Br)]BF4 (2b) in good yields. The products have been characterized by NMR and IR spectroscopy and mass spectrometry and the molecular structure of 2a has been determined by a single-crystal X-ray diffraction analysis (monoclinic, space group P21/m, Z = 2). [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09320776
Volume :
79
Issue :
5/6
Database :
Academic Search Index
Journal :
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences
Publication Type :
Academic Journal
Accession number :
178881765
Full Text :
https://doi.org/10.1515/znb-2024-0006