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Addition of diazonium salts to the coordinatively unsaturated core of a dinuclear organoruthenium complex.
- Source :
-
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences . Jun2024, Vol. 79 Issue 5/6, p327-330. 4p. - Publication Year :
- 2024
-
Abstract
- The reaction of [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)] (1) with the diazonium salts [PhN2]BF4 and [p-BrC6H4N2]BF4 in dichloromethane at T = 273 K was investigated. The oxidative addition afforded the products [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2Ph)]BF4 (2a) and [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2C6H4-p-Br)]BF4 (2b) in good yields. The products have been characterized by NMR and IR spectroscopy and mass spectrometry and the molecular structure of 2a has been determined by a single-crystal X-ray diffraction analysis (monoclinic, space group P21/m, Z = 2). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09320776
- Volume :
- 79
- Issue :
- 5/6
- Database :
- Academic Search Index
- Journal :
- Zeitschrift für Naturforschung B: A Journal of Chemical Sciences
- Publication Type :
- Academic Journal
- Accession number :
- 178881765
- Full Text :
- https://doi.org/10.1515/znb-2024-0006