Obliquity Pacing of Deep Pacific Carbonate Chemistry During the Plio‐Pleistocene.

Reconstruction of the seawater carbonate system is essential for an improved understanding of glacial‐interglacial oceanic carbon cycling and climate change. However, continuous high‐resolution ocean carbonate chemistry data are generally lacking for the Plio‐Pleistocene. Here, we present a deep Pacific carbonate ion saturation state (Δ[CO32−]) record spanning the last 5.1 Myr, reconstructed from the size‐normalized shell weight of planktonic foraminifer in the western tropical Pacific. Deep Pacific Δ[CO32−] has been modulated primarily by orbital obliquity since 5.1 Ma, during which it has exhibited in‐phase behavior with the 40‐Kyr obliquity cycle. Significantly, the amplitude of the 40‐Kyr Δ[CO32−] cycles has responded linearly to obliquity forcing throughout the Plio‐Pleistocene, independent of the late Pliocene intensification of Northern Hemisphere glaciation. We speculate that the obliquity signal in the deep Pacific Δ[CO32−] record reflects an ocean‐atmosphere circulation feedback mediated by migration of the Southern Hemisphere Westerlies. Plain Language Summary: The ocean has played an important role in controlling glacial‐to‐interglacial atmospheric pCO2 variation through changes in its carbon inventory. To decipher the patterns and drivers of the oceanic carbon cycle and climate change through glacial cycles, we provide a continuous Plio‐Pleistocene deep Pacific carbonate ion saturation state (Δ[CO32−]) at orbital time scales. The deep PacificΔ[CO32−] has been modulated by orbital forcing since 5.1 Ma, a time interval during which it has exhibited in‐phase behavior with the 40‐Kyr obliquity cycle as well as a linear response of Δ[CO32−] amplitude to obliquity range. We speculate that Plio‐Pleistocene glacial cycles of the deep Pacific carbon storage were linked to variation in Southern Hemisphere upwelling rates yoked to meridional migration of the Westerlies. Key Points: Deep Pacific Δ[CO32−] has been modulated primarily by orbital obliquity since 5.1 Ma40‐Kyr Δ[CO32−] cycles were in‐phase with and responded linearly to 40‐Kyr band obliquity forcingPlio‐Pleistocene glacial cycles of deep Pacific carbon storage were linked to meridional migration of the Southern Hemisphere Westerlies [ABSTRACT FROM AUTHOR]