Structure, magnetism and magnetocaloric properties in performance GdClWO4 compound.

Rare earth elements possessing a diverse range of optical, electrical, and magnetic properties has attracted more attention. In the present work, GdClWO 4 compound with monoclinic structure was prepared, the structure, magnetism and magnetocaloric effect (MCE) were investigated. The magnetic phase transition temperature (T N), magnetic ground state and maximum magnetic entropy change ( − Δ S M max) were derived from magnetization measurements. Both first principles calculation and experimental results suggest that the compound displays antiferromagnetic (AFM) interactions, with a magnetic transition occurring at 0.6 K, shifting from a paramagnetic (PM) state to an AFM state. The − Δ S M max is up to 35.2 J kg−1 K−1 (205.9 mJ cm−3 K−1) for GdClWO 4 at T = 1.3 K under a magnetic field change of 0–50 kOe. In particular, the volumetric magnetic entropy change still remains 83.1 mJ cm−3 K−1 at 0.5 K and μ 0 Δ H = 20 kOe, which is almost twice as much as that of commercial refrigerant Gd 3 Ga 5 O 12 (GGG) under μ 0 Δ H = 20 kOe, establishing GdClWO 4 compound as a potential candidate for cryogenic refrigeration applications. [ABSTRACT FROM AUTHOR]