Use of the inverse method to determine the thermal properties of liquid n-octadecane accounting for natural convection effect.

• Influence of natural convection on the experimental characterization of liquid thermal conductivity of octadecane. • Inverse method based on heat flux measurements to characterize the thermal conductivity and specific heat capacity of the PCM at liquid state. • A comparison of the Nusselt numbers estimated from combining the numerical and experimental results with the known correlations for the different experimental conditions was carried out. This paper numerically makes use of the inverse method coupled with experimenal results obtained through the fluxmetric method in the Laboratoire de Génie Civil et géo-Environnement (LGCgE) to determine the specific heat, thermal conductivity and thermal expansion coefficient of liquid n -octadecane in an enclosure accounting for natural convection present in the experimental system. The impact of ommiting the presence of natural convection for the thermophysical propertie determination is studied and shows very little effect on the specific heat value but a large error (by a factor of two in this study) on the thermal conductivity value. The correct properties identified when accounting for natural convection (ρ = 2150 J/kg‧K; k = 0.16 W/m‧K; β = 9.38 × 10−4 K−1) are consistent with the literature. Additional direct numerical work was done to determine the impact of using the different thermal conductivity values, comparing numerical to additional expermental restuls where natural convection was stronger. The thermal conductivity value played a minial role when simulating the behavior of the systems rightly accounting for natural convection. Combining the numerical and experimental resutls allowed the calculation of encolsure specific Nusselt numbers for the various experimental conditions used and a comparison to known correlations. It was determine that the Nusselt number obtained in the liquid n -octadecane were larger by 10 to 48%. [ABSTRACT FROM AUTHOR]