A luminescent polymeric silver(I) coordination tubular helicate

Authors :: Han, Lei
Yuan, Daqiang
Xu, Yanqing
Wu, Mingyan
Gong, Yaqiong
Wu, Benlai
Hong, Maochun
Source :: Inorganic Chemistry Communications. Jun2005, Vol. 8 Issue 6, p529-532. 4p.
Publication Year :: 2005
Abstract: Abstract: A new polymeric silver(I) coordination polymer, {[Ag(tptb)(MeCN)]ClO4} n (1), (tptb=2,4,6-trimethyl-1,3,5-tris(2-pyrimidinylthiomethyl)benzene), was synthesized by self-assembly reaction of tptb and AgClO4, and structurally characterized to be a isolated, 1D tubular helicate. 1 is luminescent and displays an emissive maximum at 510nm in the solid state at room temperature. [Copyright &y& Elsevier]