Adoption of advanced coal gasification: A panacea to carbon footprint reduction and hydrogen economy transition in South Africa.

South Africa is an energy-intensive developing country in Africa and ranked as the 1st and 14th emitter of greenhouse gas (GHG) in Africa and the world, respectively. The abundance and availability of coal in South Africa make it the mainstay primary source of energy contributing 56% of national total GHG emissions. This paper focused on the duo of energy generation and emission associated with coal processing and utilization in South Africa, and the urgent need to advance coal processing technologies marked by high carbon footprints in consonance with the sustainable development goals. Different gasification techniques and their performances have been compiled and discussed. The economic, environmental impact, energetic, and exergetic characteristics of existing hydrogen production technologies for renewable and non-renewable energy sources have been examined along with hydrogen production from plasma gasification of coal. Hydrogen production via coal or coal/biomass plasma gasification technology (nuclear-, wind-, PV solar-, and concentrated solar power-driven) in addition to carbon capture technology for transforming the captured CO 2 into value-added products appears to be the most viable option to considerably reduce emissions and meet the energy demand of South Africa. This proposed technology can be pivotal to achieving a low-carbon economy (medium-term) and transition to hydrogen economy (long-term) as championed by the global sustainable development agenda. Conclusively, hydrogen (stored in different forms e.g., liquid hydrogen, ammonia, and organic hydride) seems to find more applications (in the space industry, transport, energy storage, defense industry, etc.) than coal owing to its immediate use in distribution/demand centers and remote areas. • Coal is the primary energy source of South Africa and key driver of national CO 2 emissions. • Traditional coal gasification technologies are marked by high CO 2 emissions. • Coal plasma gasification technology is a viable option for low-carbon energy economy. • Hydrogen production via coal or coal/biomass plasma gasification technology leads to zero-carbon economy. • This immensely supports the drive towards attaining the sustainable development goals. [ABSTRACT FROM AUTHOR]