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Recovery of Vanadium from Carbonated Solution by Extraction with Transformed Aliquat 336 and Stripping-Precipitation.
- Source :
-
Solvent Extraction & Ion Exchange . 2024, Vol. 42 Issue 3, p216-238. 23p. - Publication Year :
- 2024
-
Abstract
- The leaching solution from the direct reduction-sodium smelting process of ultra-poor vanadium-bearing titanomagnetite contained sodium, vanadium, and impurities. It was carbonated to ensure sodium recovery, and the recovery of vanadium proved challenging. This study proposed and optimized a novel process of extracting vanadium from this alkaline carbonated solution using the transformed organic phase of 20 vol% (0.44 mol/L) Aliquat 336, 8 vol% 2-octanol, and 72 vol% sulfonated kerosene. To achieve superior vanadium extraction, Aliquat 336 in the organic phase was transformed into carbonate type by successively washing with NaHCO3 and NaOH solutions. The single-stage extraction efficiency of vanadium exceeded 85% at a pH of 8.0‒9.0 and an organic-to-aqueous phase ratio of 1:1. The thermodynamics of the vanadium extraction process was examined, confirming that the extraction process is an exothermic reaction (ΔH0 = −9.56 kJ/mol). Furthermore, using a solution of 4 mol/L NH4Cl and 1 mol/L NH4OH with a pH of 8.8 as the effective stripping reagent to realize one-step stripping and precipitation of vanadium, the single-stage stripping efficiency of vanadium was 99.8%, and the precipitation efficiency was about 95%. Through this stripping-precipitation process, solid ammonium metavanadate with a purity of 98.14% was obtained in one step. The mechanisms of transformation, extraction, and stripping were studied via infrared spectra of the organic phases. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 07366299
- Volume :
- 42
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Solvent Extraction & Ion Exchange
- Publication Type :
- Academic Journal
- Accession number :
- 178418899
- Full Text :
- https://doi.org/10.1080/07366299.2024.2371415