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Effect of white mud on carbonation resistance of alkali activated slag.

Authors :
Bu, Linglai
Sun, Renjuan
Guan, Yanhua
Fang, Chen
Ge, Zhi
Ran, Yao
Zhang, Hongzhi
Source :
Construction & Building Materials. Aug2024, Vol. 438, pN.PAG-N.PAG. 1p.
Publication Year :
2024

Abstract

White mud (WM) is a solid waste produced in the process of papermaking and it remains to be effectively utilized. It contains a large amount of CaCO 3 and residual alkali metal ions. This paper aims to explore the effect of WM on carbonation resistance of alkali activated slag. The changes in mechanical properties and microstructure of alkali activated white mud/slag (AAWS) after natural carbonation and accelerated carbonation were analyzed. The results indicate that the mechanisms of natural carbonation and accelerated carbonation are different. The carbonation depth achieved in 90 days of natural carbonation can be reached in just 14 days of accelerated carbonation. Samples with 15 wt% WM blended possesses the smallest carbonation depth and the highest compressive strength. WM can effectively mitigate the natural carbonation of AAWS by dissolving Mg2+ and Ca2+. Mg2+ can migrate to increase the solubility of calcite, promote the generation of hydrotalcite to absorb carbon dioxide, and reduce the carbonation degree. Ca2+ will migrate after the carbonation and decalcification of the gel product and reduce the decalcification sensitivity. This study offers a sustainable approach for improving the carbonation resistance of AAWS. • WM inclusion promotes the generation of hydrotalcite for CO 2 absorption. • The migration of Mg2+ from WM increases the solubility of calcite and promotes the formation of aragonite and vaterite. • Ca2+ dissolved from WM reduces the decalcification sensitivity of AAWS. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09500618
Volume :
438
Database :
Academic Search Index
Journal :
Construction & Building Materials
Publication Type :
Academic Journal
Accession number :
178335630
Full Text :
https://doi.org/10.1016/j.conbuildmat.2024.137207