Phase structure and electrical properties of (Ba1/2Sr1/2)2+ modified high Curie temperature CaBi2Nb2O9‐based ceramics.

High‐temperature piezoelectric sensing is usually used in the aerospace, automotive, and power plant fields. High temperature piezoelectric ceramics are considered the key materials in these fields. In this paper, Ca1−x(Ba1/2Sr1/2)xBi2Nb1.985(W3/4Mn1/4)0.015O9 (x = 0.05, 0.10, 0.15 and 0.20) (C1−xBSxBNWM) has been synthesized by a traditional solid state reaction method. The effects of substitution of calcium at the A‐site by barium and strontium on phase evolution and piezoelectric properties of the CaBi2Nb2O9 orthorhombic Aurivillius phases were investigated. The crystal structure of piezoelectric ceramics was characterized by XRD, Rietveld refinement, and Raman spectroscopy. Co‐substitution of barium/strontium (Ba2+/Sr2+) and tungsten/manganese (W6+/Mn4+) resulted in lattice distortion of C1−xBSxBNWM ceramics. The results induce that the tetragonal crystal structure increase with increasing the co‐substitution cations. Isothermal impedance spectroscopy confirmed intrinsic thermally activated conduction in the system. The C1−xBSxBNWM ceramics with x = 0.15 exhibit a very high Curie temperature (TC ∼ 923°C), a reasonable piezoelectric coefficient (d33 = 13.3 pC/N). Remarkably, even after thermal annealing at temperatures up to 800°C, it still retains a high d33 of 13 pC/N. In addition, the C0.85BS0.15BNWM ceramic had a relatively high resistivity (3.82 × 106 Ω·cm, 500°C). The Ca0.85(Ba1/2Sr1/2)0.15Bi2Nb1.985(W3/4Mn1/4)0.015O9 ceramics make possible their application in high‐temperature acceleration transducers. [ABSTRACT FROM AUTHOR]