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The enhanced toughness and growth kinetics in HfxTa2O2x+5 through modulated structure.
- Source :
-
Ceramics International . Sep2024:Part B, Vol. 50 Issue 17, p30381-30392. 12p. - Publication Year :
- 2024
-
Abstract
- Although Hf x Ta 2 O 2 x+ 5 shows great potential as a next-generation thermal barrier coating (TBC) material, the diversity of its potential modulated structures presents challenges in determining their mechanical properties. Hf x Ta 2 O 2 x+ 5 (x = 4, 6, 8) ceramics were successfully fabricated using the sol–gel method. Research on growth kinetics has indicated that grain boundary diffusion is the speed-controlling step. The activation energy increased with a larger modulated structure. In addition, the fracture toughness also increased from 1.98 MPa m1/2 for Hf 4 Ta 2 O 13 to 3.30 MPa m1/2 for Hf 8 Ta 2 O 21. Density functional theory calculations revealed that Hf x Ta 2 O 2 x+ 5 exhibited intrinsic ductility owing to the denser packing of atoms in its larger modulated structure. Thus, the tight-knit chemical bond net may contribute to a large surface energy. The results of this study provide deep insights into the toughening mechanism of modulated structures and pave the way for the design of next-generation TBCs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 50
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 178090925
- Full Text :
- https://doi.org/10.1016/j.ceramint.2024.05.334