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Photoredox/Bismuth Relay Catalysis Enabling Reductive Alkylation of Nitroarenes with Aldehydes.
- Source :
-
Chemistry - A European Journal . 7/16/2024, Vol. 30 Issue 40, p1-5. 5p. - Publication Year :
- 2024
-
Abstract
- The effective transition metal‐free photoredox/bismuth dual catalytic reductive dialkylation of nitroarenes with benzaldehydes has been reported. The nitroarene reduction through visible light‐driven photoredox catalysis was integrated with subsequent reductive dialkylation of anilines under bismuth catalysis to enable the cascade reductive alkylation of nitroarenes with carbonyls. Salient features of this relay catalysis system include mild reaction conditions, no requirement for transition metal catalysts, easy handling, step‐economy, and high selectivity. [ABSTRACT FROM AUTHOR]
- Subjects :
- *TRANSITION metal catalysts
*NITROAROMATIC compounds
*BISMUTH
*CATALYSIS
*ALKYLATION
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 30
- Issue :
- 40
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 179140145
- Full Text :
- https://doi.org/10.1002/chem.202401456