Preparation and evaluation of S-rGO/ZnFe2O4/NiCoLDH nanocomposite electrocatalyst in oxygen reduction reaction.

This study introduces a novel combination of sulfur-doped reduced graphene oxide (S-rGO), zinc ferrite (ZnFe 2 O 4) and nickel cobalt layered double hydroxide (NiCoLDH) as an efficient and low-cost electrocatalyst for oxygen reduction reaction (ORR) for the first time. The hydrothermal method is used to synthesize all samples including graphene oxide (GO), S-rGO, NiCoLDH, ZnFe 2 O 4 and S-rGO/ZnFe 2 O 4 /NiCoLDH hybrids. X-ray diffraction (XRD) analysis, field emission scanning electron microscope (FESEM), transmission electron microscopy (TEM), energy dispersive x-ray analysis (EDX), electrochemical surface area (ECSA), and fourier transform infrared spectroscopy (FTIR) analysis are used to determine the structure of synthesized electrocatalysts, physical properties, and morphology. The electrochemical measurements are carried out using cyclic voltammetry (CV), linear scanning voltammetry (LSV), chronoamperometry (ChA), and electrochemical impedance spectroscopy (EIS). The results for all samples are compared with the Pt/C commercial catalyst. According to the electrochemical results, the S-rGO/ZnFe 2 O 4 /NiCoLDH electrocatalyst has the best electrochemical performance. Moreover, the nanocomposite exhibited better electrocatalysis, a high diffusion limiting current density of −5.4 mA cm−2 and an onset potential of 0.03 V. Based on the results of this study, the LDH enhances electrical conductivity, electrocatalytic activity, active surface area, and stability of the catalyst for ORR after combining with carbon bases and ferrite. [Display omitted] • An electrochemical method was utilized for NiCo-LDH on S-rGO/ZnFe 2 O 4. • S doped reduced graphene oxide was used in a composite for improving its ORR activity. • NiCo-LDH was used as electrocatalyst for ORR. • S-rGO/ZnFe 2 O 4 /NiCo-LDH hybrid showed better ORR activity. [ABSTRACT FROM AUTHOR]