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Intermolecular π-π interactions-induced aggregation based on bispyrene for ultrasensitive detection of picric acid (PA) and 2,4-dinitrophenol (DNP).
- Source :
-
Microchemical Journal . Jul2024, Vol. 202, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
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Abstract
- [Display omitted] • Simple bispyrene-based probe (BisPyH) with aggregation-induced enhanced emission for PA and DNP ultrasensitive detection, respectively was constructed. • BisPyH exhibited relatively bright green intermolecular excimer emission with AIEE effect in DMSO/H 2 O (1:1, v/v) via intermolecular π-π interactions among pyrene units. • Qualitative and quantitative detection of PA or DNP in real water. • Naked-eye detection of PA or DNP in solid state by TLC plates and test strips. It was still important to explore excimer emission-based fluorescence probes for nitroaromatics detection by formation or destruction of pyrene excimer with strong emission change. In this work, we have synthesized a simple bis(pyrene) derivative (BisPyH) and studied its optical behavior by using UV–vis and fluorescent spectroscopy. In pure DMSO solution, it emitted a weak blue fluorescence due to the formation of excimer states, on the contrary, the BisPyH in the DMSO/H 2 O (v/v, 1:1) mixture solution was self-assembled to form aggregates via intermolecular π-π interactions among pyrene units, giving almost 10-fold fluorescence enhancement compared to that in pure DMSO solution. The formed aggregates just offered a perfect platform for the selective detection PA and DNP explosives by quenching the bright green intermolecular-excimer emission in competitive environment. BisPyH exhibited a limit of detection (LOD) towards PA, and DNP as low as 7.32 × 10−8, and 8.11 × 10−8 M, respectively. Subsequently, the fluorescence quenching mechanism was demonstrated by the density functional theory (DFT), UV–vis and fluorescence spectra, SEM, and the quenching constants. Furthermore, filter paper strips and thin-layer chromatography (TLC) plates coated with BisPyH were able to detect PA and DNP in the practical application. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0026265X
- Volume :
- 202
- Database :
- Academic Search Index
- Journal :
- Microchemical Journal
- Publication Type :
- Academic Journal
- Accession number :
- 177906246
- Full Text :
- https://doi.org/10.1016/j.microc.2024.110755