Striations in a radio frequency hydrogen discharge tube: Optical emission plasma diagnostics and Raman analysis of in situ graphite probes.

Standing striations with a unique pattern have been observed in a radio-frequency-generated hydrogen plasma. The striation pattern consists of a sequence of closely spaced bright ring doublets and two types of dark gaps of different widths. The bright and dark regions in striations were spectroscopically resolved with the Balmer series and the Fulcher band emission lines of hydrogen. Temperatures in these fine structures were determined. In general, the wider dark gap has a higher excitation temperature than the nearby narrower ones in the striation pattern sequence. Bright regions are rotationally hotter than the adjacent dark ones. However, for vibrational temperatures, the trends are not so obvious. No clear pressure dependence of temperatures was observed in striations within the pressure range of maintaining stable standing striations in this work. In addition to optical emission spectroscopy, we used graphite granules as in situ probes for plasma conditions in different striation regions. The striated hydrogen plasma-treated graphite granules were analyzed with Raman spectroscopy. The observed hydrogen-graphite interaction was correlated with the measured temperatures and the fine structures of striations in a discharge tube. [ABSTRACT FROM AUTHOR]