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Crafting in situ boron and selenium-doped carbon nitride nanosheets for turbocharged benzaldehyde to benzyl alcohol under solar spectrum.

Authors :
Gautam, Harshita
Yadav, Rajesh K.
Mishra, Shaifali
Shahin, Rehana
Singh, Satyam
Singhal, Rajat
Gupta, Navneet K.
Baeg, Jin OoK
Singh, Atul P.
El-Hiti, Gamal A.
Yadav, Krishna Kumar
Source :
Diamond & Related Materials. Jun2024, Vol. 146, pN.PAG-N.PAG. 1p.
Publication Year :
2024

Abstract

This research focuses on the fabrication and application of in situ boron and selenium-doped carbon nitride nanosheets as effective photocatalysts using sun spectrum irradiation to convert turbocharged benzaldehyde to benzyl alcohol. To optimize the doping method for enhanced activity, the effect of changing dopant concentrations on catalytic efficiency was thoroughly investigated. Furthermore, a through analysis of the reactive species involved in the conversion process helped to clarify the photocatalytic process. Based on charge transfer and low recombination, the results indicate that boron and selenium dopants work synergistically to improve catalytic efficiency. This research helps to improve the development of new photocatalytic materials for the sustainable and ecologically friendly transformation of organic molecules under solar spectrum irradiation. The regeneration of NADH using B,Se-CN photocatalyst demonstrates very good efficiency. It also demonstrated the high conversion efficiency of benzaldehyde to benzyl alcohol. This study emphasizes the possible use of B,Se-CN composite in the area of photoinduced conversion-based organic transformation. The knowledge gathered from this research opens up new avenues for the development and enhancement of effective photocatalysts that might be used in a range of solar-powered organic transformation processes. [Display omitted] • B,Se-CN photocatalyst was synthesis via two-step process through thermal polycondensation of M, B and SU. • The light harvesting photocatalyst had the capacity to photo-regenerate the 1,4 NADH and bio-transformation. • The synthesized photocatalyst potential as stable catalyst for production of 1,4 NADH (yield and benzyl alcohol. • Demonstrated synergistic enhancement of catalytic efficiency by dopants, contributing to sustainable alcohol formation. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09259635
Volume :
146
Database :
Academic Search Index
Journal :
Diamond & Related Materials
Publication Type :
Academic Journal
Accession number :
177847908
Full Text :
https://doi.org/10.1016/j.diamond.2024.111140