Advancing Pore‐Space‐Partitioned Metal–Organic Frameworks with Isoreticular Cluster Concept.

Trigonal planar M3(O/OH) trimers are among the most important clusters in inorganic chemistry and are the foundational features of multiple high‐impact MOF platforms. Here we introduce a concept called isoreticular cluster series and demonstrate that M3(O/OH), as the first member of a supertrimer series, can be combined with a higher hierarchical member (double‐deck trimer here) to advance isoreticular chemistry. We report here an isoreticular series of pore‐space‐partitioned MOFs called M3M6 <italic>pacs</italic> made from co‐assembly between M3 single‐deck trimer and M3x2 double‐deck trimer. Important factors were identified on this multi‐modular MOF platform to guide optimization of each module, which enables the phase selection of M3M6 <italic>pacs</italic> by overcoming the formation of previously‐always‐observed same‐cluster phases. The new <italic>pacs</italic> materials exhibit high surface area and high uptake capacity for CO2 and small hydrocarbons, as well as selective adsorption properties relevant to separation of industrially important mixtures such as C2H2/CO2 and C2H2/C2H4. Furthermore, new M3M6 <italic>pacs</italic> materials show electrocatalytic properties with high activity. [ABSTRACT FROM AUTHOR]