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Oxidation of Cage Derivatives of Quinopimaric Acid.
- Source :
-
Russian Journal of Organic Chemistry . Mar2024, Vol. 60 Issue 3, p423-429. 7p. - Publication Year :
- 2024
-
Abstract
- The oxidation of cage compounds derived from quinopimaric acid, namely γ-diketone, oxa-"bird cage," 18-chloro-15-oxa-"bird cage," and 16-sulfanyl-15-oxa-"bird cage," was studied using a number of oxidating agents, including sodium percarbonate in trifluoroacetic acid at 0°C, 36% hydrogen peroxide in acetone at room temperature, and tert-butyl hydroperoxide in the presence of MoCl5 in boiling benzene. It was shown for the first time that the oxidation of diterpene oxa-"bird cages" led to the formation of mixtures of keto lactones (Baeyer–Villiger oxidation products), in which 7,10-dioxo-6-oxaheptacyclo[11.8.0.03,8.04,12.05,11.09,13.016,21]heneicosane was the major component. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10704280
- Volume :
- 60
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 177775813
- Full Text :
- https://doi.org/10.1134/S1070428024030084