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High-pressure synthesis of A-site ordered perovskite PbMn3(CrMn3)O12 with long-range antiferromagnetic ordering and a spin glass transition.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 6/21/2024, Vol. 53 Issue 23, p9819-9826. 8p. - Publication Year :
- 2024
-
Abstract
- An AA′3B4O12-type perovskite oxide PbMn3(CrMn3)O12 was synthesized by high-pressure solid-state reactions at 8 GPa and 1373 K. Synchrotron X-ray diffraction shows a cubic crystal structure with the space group Im3¯. The charge states are verified by X-ray photoelectron spectroscopy to be PbMn3+3(Cr3+Mn3+2Mn4+)O12, where the Pb2+ and Mn3+ are 1 : 3 ordered respectively at A and A′ sites, while the Cr3+, Mn3+ and Mn4+ are disorderly distributed at the B site. PbMn3(CrMn3)O12 features a long-range antiferromagnetic order of A′-site Mn3+ spins at about 66 K and a subsequent spin glass transition around 36 K due to the randomly distributed Cr3+, Mn3+, and Mn4+ cations at the B site. This unique stepwise order of A′ and B-site spins indicates weak A′–B site spin interactions, which are dominated by the difference in the B-site Mn3+/Ni2+ and Mn4+ number in the quadruple perovskites AMn3B4O12. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 53
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 177774674
- Full Text :
- https://doi.org/10.1039/d4dt01357c