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Electrochemical deposition of NiO/NiCo2O4 nanostructures for high-performance supercapacitors.
- Source :
-
Materials Chemistry & Physics . Jul2024, Vol. 321, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- NiO is widely used in supercapacitors because of its low toxicity, low price and environmental friendliness. In this study, NiO/NiCo 2 O 4 composites were prepared on nickel foam substrates using a simple electrochemical deposition technique. By adjusting the deposition time in the electrochemical parameters, the optimum conditions for the deposition process can be fine-tuned. Characterization techniques such as scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) confirmed the synthesis of NiO/NiCo 2 O 4 composites. The electrochemical properties of the composite electrode NiO/NiCo 2 O 4 /NF were evaluated by cyclic voltammetry (CV), electrostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The specific capacitance (Cs) of the prepared composite electrode NiO/NiCo 2 O 4 /NF electrode was 717.8 mF/cm2 at 2 mA/cm2 with a capacitance retention of 74.8 %. In addition, Aqueous symmetric supercapacitors (SSCs) and all-solid symmetric supercapacitors were assembled based on the composite NiO/NiCo 2 O 4 /NF electrode, respectively. The aqueous SSCs have a power density of 880 μW/cm2 and an energy density of 123.0 μWh/cm2, the all-solid symmetric supercapacitors have a power density of 960 μW/cm2 and an energy density of 24.27 μWh/cm2. The series connection of two identical capacitors can light up light-emitting diodes (LEDs). This research presents a promising technique for producing Ni-based electrode material for supercapacitors. [Display omitted] • NiO/NiCo 2 O 4 composites were prepared by a simple electrodeposition method. • Specific capacitance of NiO/NiCo 2 O 4 /NF electrode: 717.8 mF/cm2 at 2 mA/cm2, with 74.8 % retention. • Aqueous SSCs based on NiO/NiCo 2 O 4 /NF: power density 880 μW/cm2, energy density 123.0 μWh/cm2. • All-solid supercapacitors based on NiO/NiCo 2 O 4 /NF: power density 960 μW/cm 2 , energy density 24.27 μWh/cm2. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02540584
- Volume :
- 321
- Database :
- Academic Search Index
- Journal :
- Materials Chemistry & Physics
- Publication Type :
- Academic Journal
- Accession number :
- 177753154
- Full Text :
- https://doi.org/10.1016/j.matchemphys.2024.129514