Cesium ion-guided detection of trichloroethylene in air.

Whereas the close associations of cesium ion with organochlorine compounds have been previously documented, the present report is the first attempt to exploit these interactions to create a trichloroethylene (TCE)-selective sensor. Gold monolayer-protected clusters peripherally functionalized with Cs+ ions were used to prepare a chemiresistance film on MEMS-fabricated interdigitated electrodes. Vapor sensing properties of the cesium-rich chemiresistor were determined using a panel of chlorinated hydrocarbons including TCE as well as polar and non-polar VOCs for comparison. The sensor was selective and highly sensitive toward VOCs containing a 1,2-dichloro group at concentrations as low as 0.1 ppm. The results suggest the key interaction contributing to sensor response is a bidentate, metallocycle-like coordination of the 1,2-dichloro group to the cesium cations at the sensor surface. [Display omitted] • Gold monolayer-protected clusters peripherally functionalized with Cs+ ions were synthesized to prepare a chemiresistor sensor. • Vapor sensing properties of the cesium-rich chemiresistor were determined using a panel of chlorinated hydrocarbons. • The sensor was selective and highly sensitive toward VOCs containing a 1,2-dichloro group \. • The key interaction contributing to sensor response is a metallocycle-like coordination of the 1,2-dichloro group to cesium cations. [ABSTRACT FROM AUTHOR]