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Visible-light-induced selective alkylsulfonylation of unactivated alkenes via remote heteroaryl migrations.

Visible-light-induced selective alkylsulfonylation of unactivated alkenes via remote heteroaryl migrations.

Authors :
Xin Yuan
Jie Liu
Hao Lv
Long-Zhou Qin
Xiu Duan
Jian Wang
Meng-Yu Wu
Beining Chen
Jiang-Kai Qiu
Kai Guo
Source :
Green Synthesis & Catalysis. May2024, Vol. 5 Issue 2, p126-130. 5p.
Publication Year :
2024

Abstract

Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO. (SO2)2 and thianthrenium salts via a distal heteroaryl migration process has been developed, which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds. These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions, followed by distal heteroaryl migration. This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
26665549
Volume :
5
Issue :
2
Database :
Academic Search Index
Journal :
Green Synthesis & Catalysis
Publication Type :
Academic Journal
Accession number :
177683516
Full Text :
https://doi.org/10.1016/j.gresc.2023.03.002